Chinese Journal of Tissue Engineering Research ›› 2024, Vol. 28 ›› Issue (5): 664-668.doi: 10.12307/2024.251
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Cheng Jinhui, Wu Quan, Peng Min, Huang Changli, Tian Huimin, Li Yang
Received:
2023-01-12
Accepted:
2023-02-14
Online:
2024-02-18
Published:
2023-08-16
Contact:
Wu Quan, MD, Associate professor, School of Mechanical and Electrical Engineering, Guizhou Normal University, Guiyang 550025, Guizhou Province, China
About author:
Cheng Jinhui, Master candidate, School of Mechanical and Electrical Engineering, Guizhou Normal University, Guiyang 550025, Guizhou Province, China
Supported by:
CLC Number:
Cheng Jinhui, Wu Quan, Peng Min, Huang Changli, Tian Huimin, Li Yang. Preparation and properties of selective laser melting of porous titanium at a low energy density[J]. Chinese Journal of Tissue Engineering Research, 2024, 28(5): 664-668.
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随着能量密度的增加,试件的孔隙率逐渐降低,在10.61-37.88 J/mm3范围内,选区激光熔化成形试件的孔隙率在4.16%-33.67%之间。将表1参数设计值与图2结果结合分析,可将成形试件按能量密度大致分为成形多孔和成形较为致密2个区域。在能量密度10.61-27.78 J/mm3区间下,能成形孔隙率11.23%-33.67%的多孔试件,该区间下能量输入不足,合金内部熔池流动性较差,无法形成良好的重叠,形成较大孔隙。同时,熔深不足造成的润湿不良也使得层与层之间出现未熔合层间孔隙[31-32]。在能量密度27.78-37.88 J/mm3区间下,随着能量密度的增加,熔池流动性提高,粉末颗粒熔化为连续熔道[33-34],试件的孔隙率降低,该区间下成形试件较为致密,孔隙率较小。 2.2 成形件物相分析 图3显示了在不同能量密度下成形的多孔钛的X射线衍射图谱。由图3A可知,Ti-6Al-4V合金粉末与成形多孔试件主要由密排六方α钛组成,β相的含量很少,可能原因为:β相晶粒非常细小,散布于α相晶界间,难以生成明显的特定β相晶面指数的衍射峰[35]。同时,与Ti-6Al-4V合金粉末X射线衍射峰相比,多孔试件的衍射峰出现轻微右移现象。这是因为小能量密度下热输入减少,加快了试件冷却速度,致使Al、V元素固溶于相结构中,又因为Al、V的原子半径小于Ti(Al:0.143 nm,V:0.134 nm,Ti:0.145 nm)[36-37],α相及β相的晶格常数降低,衍射峰右移。"
对图3A中衍射角40°-41°进行局部放大,得到图3B。由图3B可知,衍射峰最强峰的强度随着能量密度的减小逐渐降低并出现宽化现象,这是因为激光能量输入不足导致试样结晶度较差,从而造成衍射峰峰值降低且宽化的现象。 2.3 成形件微观形貌演变 图4为不同能量密度下成形的多孔钛断面微观形貌,可以发现,试件断面出现未完全熔化球形粉末颗粒,且随着能量密度的增加,颗粒数目越来越少。图4A为能量密度10.61 J/mm3下制备的试件,断面出现大量表面微熔化的球形粉末颗粒,颗粒之间轻微连接,形成烧结颈。该阶段处于典型的烧结早期烧结颈长大阶段,该阶段下原子向颗粒结合面的大量迁移使得烧结颈扩大,颗粒间距离缩小,形成具有大量连通孔隙、高比表面积的多孔钛[38-39]。图4B是图4A的放大倍数图,可清晰看到轻微连接的烧结颈及不规则条状连通孔隙,封闭孔较少,熔化的粉末颗粒间形成的小孔与球形颗粒烧结模型中烧结颈长大阶段描述一致。图4C是能量密度15.15 J/mm3下制备的试件,此时,粉末颗粒熔化程度加剧,烧结颈较图4A中长大,粉末之间熔化成团聚状,形成轻微熔道,但仍有部分粉末颗粒未完全熔化,孔隙尺寸较之前变小,不规则连通孔仍然是该能量密度下的主要孔隙组成。能量密度的增加主要表现为烧结颈和孔隙尺寸的变化。图4D是能量密度20.83 J/mm3下制备的试件,该能量密度下粉末熔化程度加剧,能清晰看到层与层之间的熔道,但仍有未完全熔化的粉末颗粒,出现近球形封闭孔隙,该阶段下孔隙以连通孔和近球形封闭孔为主。"
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